Free Jet Cooled Laser - Induced Fluorescence Spectrum of Methoxy . 1 . Vibronic Analysis of the and 2 States
نویسندگان
چکیده
The methoxy free radical has been formed in a supersonic free jet expansion by KrF photolysis of methyl nitrite. Its laser-induced fluorescence excitation and wavelength-resolved-emission _spectra have been recorded at low temperature. This paper reports the vibronic analysis of the C H 3 0 and CD30 A2Al XZE electronic spectra. A new value for the electronic origin has been determined as well as a nearly complete set of vibrational frequencies.
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